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Thermal conversion of (SCN)2 slim movies right into the spin crossover complicated Fe(phen)2(NCS)2† †


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a Division of Chemistry, The College of Alabama, Box 870336, Tuscaloosa, AL, U.S.A. Email: gjs

Home heating the spin-crossover (SCO) facility FeII(phen)2(NCS)2 (phen = 1,10-phenanthroline) under high vacuum cleaner leads to the development of red movies that have actually been determined as (SCN)2 by IR, Raman, as well as UV-Vis spectroscopy. After annealing the red movies to ∼ 140 ° C under vacuum cleaner, purple (paramagnetic) movies have as well as develop been recognized as Fe(phen)2(NCS)2 by SQUID magnetometry, X-ray photoelectron, Raman and also IR spectroscopy. The Fe(phen)2(NCS)2 movies display a SCO change at ∼ 180 K with an expanded change temperature level variety in between the high-spin and also low-spin states (∼ 20 K) when contrasted to the mass stage, which is credited a wide circulation of molecular atmospheres.


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DOI https://doi.org/10.1039/C3RA22534H
Post kind Paper
Sent 16 Oct 2012
Accepted 09 Jan 2013
First released 06 Feb 2013

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csseleven.com Adv. , 2013, 3 , 3745-3754
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Thermal conversion of (SCN)2 slim movies right into the spin crossover complicated Fe(phen)2(NCS)2

E. C. Ellingsworth, B. Turner and also G. Szulczewski, csseleven.com Adv., 2013, 3 , 3745 DOI: 10.1039/ C3RA22534H

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Edward C. Ellingsworth
Brittany Turner
Greg Szulczewski

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